where can i find heart scales
Smashing rocks, Pokepon machine in Sonata City, Battle Frontier in Roggan Town, held by luvdiscs, pickup, and probably more.
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where can i find luvdiscs
You can fish them in ponds and lakes. I heard the body of water within Midna Mine was particularly good. I recommend you lead with a pokemon with the ability CompoundEyes in order to increase the chance they hold a scale and use a move like covet or thief to take it.
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thx a lot